Application of Sol-Gel Synthesized Cu-TiO₂/ZnO Photocatalyst for Textile Dye Wastewater Treatment
Keywords:
Industry, Methylene Blue, PhotocatalystAbstract
The textile dyeing industry is the second largest water polluter in the world, with the industry generating 20% of the world's total wastewater effluent. Methylene blue is one of the most commonly used textile dyes, causing degradation of aquatic ecosystem quality. A new method that can help in the treatment process of liquid waste that has a relatively low cost, one of which is a photocatalyst using material and using the sol gel method. This photocatalyst was tested by characterization using SEM, UV-Vis DRS, and UV-Vis Spectrometer. The results of SEM characteristics show that the particles are spherical with varying particle sizes. The UV-Vis DRS results show that the Eg values obtained are 3.186 eV for TiO₂/ZnO, 2.296 eV for Cu(5%)-TiO₂/ZnO, and 2.162 eV for Cu(8%)-TiO₂/ZnO. The concentration of methylene blue affects the effectiveness of degradation with the highest degradation at 5 ppm of 77.51%, at 10 ppm of 67.02% and 15 ppm of 54.30%. In conclusion, the sol-gel synthesized Cu-TiO₂/ZnO photocatalyst demonstrates promising effectiveness for textile dye wastewater treatment, with optimized Cu doping significantly enhancing visible-light absorption and degradation efficiency of methylene blue.References
A. Z. Wathoni, N. Q. Faagna, and A. I. Pratiwi, “Pengaruh Aktivitas Industri Terhadap Kualitas Air Sungai Kabupaten Karawang,” Ind. Xplore, vol. 9, no. 1, pp. 368–377, 2024, doi: 10.36805/teknikindustri.v9i1.6486.
J. Stokes, “Textile industry: water management.” [Online]. Available: https://pciaw.org/textile-industry-water-management/
S. N. Sakinah, Julinawati, Fathurrahmi, and Sheilatina, “Immobilisasi Α-Fe2O3/Bentonit Sebagai Fotokatalis Pada Fotodegradasi Zat Warna Methylene Blue,” J. Glob. Ilm., vol. 2, no. 3, pp. 1–10, 2024.
D. Ariyanti, F. Wicaksana, and W. Gao, “Submerged Membrane Photo Reactor (SMPR) with Simultaneous Photo Degradation and TiO2 Catalyst Recovery for Efficient Dyes Removal,” ASEAN J. Chem. Eng., vol. 21, no. 2, 2021, doi: 10.22146/ajche.65952.
M. Ikram et al., “Biodegradation of Azo Dye Methyl Red by Pseudomonas aeruginosa: Optimization of Process Conditions,” Int. J. Environ. Res. Public Health, vol. 19, no. 16, 2022, doi: 10.3390/ijerph19169962.
S. K. Kamarudin, W. R. W. Daud, M. S. Ayub, A. W. Mohammad, and S. E. Lyuke, “A Review on Fuel Cell as Advanced Power Source,” ASEAN J. Chem. Eng., vol. 2, no. 1, 2008, doi: 10.22146/ajche.50806.
M. Fahmi, M. Febriansyah, R. Yudianti, and M. Ibadurrohman, “Comparative study of g- C₃N₄ / Cu₂O and BiVO₄ / Cu₂O photocathodes for enhanced electricity generation and hydrogen evolution in photocatalytic fuel cells,” vol. 15, no. 1, pp. 191–203, 2026.
S. Babel, P. A. Sekartaji, and H. Sudrajat, “TiO2 as an effective nanocatalyst for photocatalytic degradation of humic acid in water environment,” J. Water Supply Res. Technol. - AQUA, vol. 66, no. 1, 2017, doi: 10.2166/aqua.2016.102.
A. N. El-Shazly, A. H. Hegazy, E. T. El Shenawy, M. A. Hamza, and N. K. Allam, “Novel facet-engineered multi-doped TiO2 mesocrystals with unprecedented visible light photocatalytic hydrogen production,” Sol. Energy Mater. Sol. Cells, vol. 220, 2021, doi: 10.1016/j.solmat.2020.110825.
M. M. Ali, M. J. Haque, M. H. Kabir, M. A. Kaiyum, and M. S. Rahman, “Nano synthesis of ZnO–TiO2 composites by sol-gel method and evaluation of their antibacterial, optical and photocatalytic activities,” Results Mater., vol. 11, p. 100199, 2021, doi: 10.1016/j.rinma.2021.100199.
N. Suganthi, S. Thangavel, and K. Kannan, “Hibiscus subdariffa leaf extract mediated 2-D fern-like ZnO/TiO2 hierarchical nanoleaf for photocatalytic degradation,” FlatChem, vol. 24, no. July, p. 100197, 2020, doi: 10.1016/j.flatc.2020.100197.
N. R. Khalid, E. Ahmed, Z. Hong, M. Ahmad, Y. Zhang, and S. Khalid, “Cu-doped TiO2 nanoparticles/graphene composites for efficient visible-light photocatalysis,” Ceram. Int., vol. 39, no. 6, 2013, doi: 10.1016/j.ceramint.2013.02.051.
L. Tian, Z. Li, X. Xu, and C. Zhang, “Advances in noble metal (Ru, Rh, and Ir) doping for boosting water splitting electrocatalysis,” Journal of Materials Chemistry A, vol. 9, no. 23. 2021. doi: 10.1039/d1ta01108a.
S. Preda et al., “Photocatalytic and Antibacterial Properties of Doped TiO2 Nanopowders Synthesized by Sol−Gel Method,” Gels, vol. 8, no. 10, pp. 1–20, 2022, doi: 10.3390/gels8100673.
A. Adamu, M. Isaacs, K. Boodhoo, and F. R. Abegão, “Investigation of Cu/TiO2 synthesis methods and conditions for CO2 photocatalytic reduction via conversion of bicarbonate/carbonate to formate,” J. CO2 Util., vol. 70, 2023, doi: 10.1016/j.jcou.2023.102428.
Nasikhudin, M. Diantoro, A. Kusumaatmaja, and K. Triyana, “Study on Photocatalytic Properties of TiO2 Nanoparticle in various pH condition,” in Journal of Physics: Conference Series, 2018. doi: 10.1088/1742-6596/1011/1/012069.
T. Degabriel et al., “Factors impacting the aggregation/agglomeration and photocatalytic activity of highly crystalline spheroid- and rod-shaped TiO2 nanoparticles in aqueous solutions,” Phys. Chem. Chem. Phys., vol. 20, no. 18, 2018, doi: 10.1039/c7cp08054a.
N. Sondezi, Z. Njengele-Tetyana, K. P. Matabola, and T. A. Makhetha, “Sol-Gel-Derived TiO2 and TiO2/Cu Nanoparticles: Synthesis, Characterization, and Antibacterial Efficacy,” ACS Omega, vol. 9, no. 14, pp. 15959–15970, 2024, doi: 10.1021/acsomega.3c09308.
F. Pellegrino et al., “Influence of agglomeration and aggregation on the photocatalytic activity of TiO2 nanoparticles,” Appl. Catal. B Environ., vol. 216, 2017, doi: 10.1016/j.apcatb.2017.05.046.
D. Sugandi, N. Wahyuni, and W. Rahmalia, “Fotocatalytic degradation of methylene blue by floating TiO2-coconut fiber,” Acta Chim. Asiana, vol. 7, no. 1, pp. 437–442, 2024, doi: 10.29303/aca.v7i1.183.
M. Sahu and P. Biswas, “Single-step processing of copper-doped titania nanomaterials in a flame aerosol reactor,” Nanoscale Res. Lett., vol. 6, 2011, doi: 10.1186/1556-276X-6-441.
M. R. Delsouz Khaki, M. S. Shafeeyan, A. A. A. Raman, and W. M. A. W. Daud, “Enhanced UV–Visible photocatalytic activity of Cu-doped ZnO/TiO2 nanoparticles,” J. Mater. Sci. Mater. Electron., vol. 29, no. 7, 2018, doi: 10.1007/s10854-017-8515-9.
L. Li et al., “Surface doping for photocatalytic purposes: Relations between particle size, surface modifications, and photoactivity of SnO2:Zn 2+ nanocrystals,” Nanotechnology, vol. 20, no. 15, 2009, doi: 10.1088/0957-4484/20/15/155706.
D. Kevin, “PENGARUH VARIASI MASSA Cu DAN SUHU KALSINASI PADA SINTESIS FOTOKATALIS Cu-TiO2/ZnO UNTUK DEGRADASI METHYLENE BLUE DALAM PHOTOCATALYTIC FUEL CELL (PFC),” J. Inov. Tek. Kim., vol. 10, no. 2, pp. 100–112, 2025, doi: 10.31942/inteka.v10i2.13076.
T. M. Abdel-Fattah, A. Wixtrom, K. Zhang, W. Cao, and H. Baumgart, “Highly Uniform Self-Assembled Gold Nanoparticles over High Surface Area ZnO Nanorods as Catalysts,” ECS J. Solid State Sci. Technol., vol. 3, no. 10, 2014, doi: 10.1149/2.0211410jss.
T. S. Putri, S. Dampang, M. F. Hakim, F. Yuliasari, D. Kevin, and C. P. Meylani, “Pengaruh Luas Permukaan Material Fotokatalis Cu-TiO 2 / ZnO dan Larutan HCl Terhadap Degradasi Methylene Blue dalam Photocatalytic Fuel Cell,” vol. X, no. 4, pp. 15202–15209, 2025.
X. J. Yang, S. Wang, H. M. Sun, X. B. Wang, and J. S. Lian, “Preparation and photocatalytic performance of Cu-doped TiO2 nanoparticles,” Trans. Nonferrous Met. Soc. China (English Ed., vol. 25, no. 2, pp. 504–509, 2015, doi: 10.1016/S1003-6326(15)63631-7.
R. Yusoff et al., “Physical properties of aqueous mixtures of N-methyldiethanolamine (MDEA) and ionic liquids,” J. Ind. Eng. Chem., vol. 20, no. 5, pp. 3349–3355, 2014, doi: 10.1016/j.jiec.2013.12.019.
R. Mohan, K. Krishnamoorthy, and S. J. Kim, “Enhanced photocatalytic activity of Cu-doped ZnO nanorods,” Solid State Commun., vol. 152, no. 5, pp. 375–380, 2012, doi: 10.1016/j.ssc.2011.12.008.
D. A. H. Hanaor and C. C. Sorrell, “Review of the anatase to rutile phase transformation,” J. Mater. Sci., vol. 46, no. 4, pp. 855–874, 2011, doi: 10.1007/s10853-010-5113-0.
R. Zha, R. Nadimicherla, and X. Guo, “Ultraviolet photocatalytic degradation of methyl orange by nanostructured TiO2/ZnO heterojunctions,” J. Mater. Chem. A, vol. 3, no. 12, 2015, doi: 10.1039/c5ta00764j.
Q. Ayun, R. Ridho, and E. Malis, “Pengaruh Pelapisan Titanium Dioksida (Tio2) Pada Plat Kaca Terhadap Efektivitas Fotodegradasi Methyl Orange Menggunakan Metode Sodis (Solar Disinfection Water),” J. Cryst. Publ. Penelit. Kim. dan Ter., vol. 2, no. 1, pp. 37–50, 2020, doi: 10.36526/jc.v2i1.924.
C. Putri Meylani, Sarah Dampang, Muhammad Fahmi Hakim, Fitri Yuliasari, David Kevin, and Tarishah Setyowati Putri, “Pengaruh Konsentrasi Methylene Blue dan NaClO pada Proses Degradasi Photocatalytic Fuel Cell Menggunakan Elektroda Cu-TiO2/ZnO,” J. Tek. Kim. USU, vol. 14, no. 2, 2025, doi: 10.32734/jtk.v14i2.20525.
S. K. Kansal, M. Singh, and D. Sud, “Studies on photodegradation of two commercial dyes in aqueous phase using different photocatalysts,” J. Hazard. Mater., vol. 141, no. 3, 2007, doi: 10.1016/j.jhazmat.2006.07.035.
S. Sakthivel, B. Neppolian, M. V. Shankar, B. Arabindoo, M. Palanichamy, and V. Murugesan, “Solar photocatalytic degradation of azo dye: Comparison of photocatalytic efficiency of ZnO and TiO2,” Sol. Energy Mater. Sol. Cells, vol. 77, no. 1, 2003, doi: 10.1016/S0927-0248(02)00255-6.
A. Lau et al., “Visible-light Degradation of Methylene Blue using Energy-Efficient Carbon-Doped TiO2: Kinetic Study and Mechanism,” Bull. Chem. React. Eng. Catal., vol. 20, no. 1, pp. 177–192, 2025, doi: 10.9767/bcrec.20347.
H. Chen, N. Chen, Y. Gao, and C. Feng, “Photocatalytic degradation of methylene blue by magnetically recoverable Fe3O4/Ag6Si2O7 under simulated visible light,” Powder Technol., vol. 326, 2018, doi: 10.1016/j.powtec.2017.12.029.
T. Fotiou, T. M. Triantis, T. Kaloudis, and A. Hiskia, “Evaluation of the photocatalytic activity of TiO2 based catalysts for the degradation and mineralization of cyanobacterial toxins and water off-odor compounds under UV-A, solar and visible light,” Chem. Eng. J., vol. 261, 2015, doi: 10.1016/j.cej.2014.03.095.
P. O. Oladoye, T. O. Ajiboye, E. O. Omotola, and O. J. Oyewola, “Methylene blue dye: Toxicity and potential elimination technology from wastewater,” Results in Engineering, vol. 16. 2022. doi: 10.1016/j.rineng.2022.100678.
M. R. Delsouz Khaki, M. S. Shafeeyan, A. A. A. Raman, and W. M. A. W. Daud, “Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation,” J. Mol. Liq., vol. 258, 2018, doi: 10.1016/j.molliq.2017.11.030.
S. L. Lee et al., “Role of dissolved oxygen on the degradation mechanism of Reactive Green 19 and electricity generation in photocatalytic fuel cell,” Chemosphere, vol. 194, 2018, doi: 10.1016/j.chemosphere.2017.11.166.
P. Li et al., “Approaches for Enhancing Wastewater Treatment of Photocatalytic Fuel Cells: A Review,” Materials (Basel)., vol. 17, no. 9, pp. 1–17, 2024, doi: 10.3390/ma17092139.
R. S. Mukkavilli et al., “Electrocatalytic activity, phase kinetics, spectroscopic advancements, and photocorrosion behaviour in tantalum nitride phases,” Nano Energy, vol. 129, no. May, 2024, doi: 10.1016/j.nanoen.2024.110046.
S. Sehar, F. Sher, S. Zhang, U. Khalid, J. Sulejmanović, and E. C. Lima, “Thermodynamic and kinetic study of synthesised graphene oxide-CuO nanocomposites: A way forward to fuel additive and photocatalytic potentials,” J. Mol. Liq., vol. 313, 2020, doi: 10.1016/j.molliq.2020.113494.
H. Tang, K. Geng, Y. Hu, and N. Li, “Synthesis and properties of phosphonated polysulfones for durable high-temperature proton exchange membranes fuel cell,” J. Memb. Sci., vol. 605, 2020, doi: 10.1016/j.memsci.2020.118107.
D. Rajamanickam and M. Shanthi, “Photocatalytic degradation of an organic pollutant by zinc oxide – solar process,” Arab. J. Chem., vol. 9, 2016, doi: 10.1016/j.arabjc.2012.05.006.
S. L. Lee et al., “Exploring the relationship between molecular structure of dyes and light sources for photodegradation and electricity generation in photocatalytic fuel cell,” Chemosphere, vol. 209, 2018, doi: 10.1016/j.chemosphere.2018.06.157.
M. A. Rauf and S. S. Ashraf, “Fundamental principles and application of heterogeneous photocatalytic degradation of dyes in solution,” Chemical Engineering Journal, vol. 151, no. 1–3. 2009. doi: 10.1016/j.cej.2009.02.026.
A. Houas, H. Lachheb, M. Ksibi, E. Elaloui, C. Guillard, and J. M. Herrmann, “Photocatalytic degradation pathway of methylene blue in water,” Appl. Catal. B Environ., vol. 31, no. 2, 2001, doi: 10.1016/S0926-3373(00)00276-9.
M. W. Kee, J. W. Soo, S. M. Lam, J. C. Sin, and A. R. Mohamed, “Evaluation of photocatalytic fuel cell (PFC) for electricity production and simultaneous degradation of methyl green in synthetic and real greywater effluents,” J. Environ. Manage., vol. 228, 2018, doi: 10.1016/j.jenvman.2018.09.038.
C. B. Ong, L. Y. Ng, and A. W. Mohammad, “A review of ZnO nanoparticles as solar photocatalysts: Synthesis, mechanisms and applications,” Renewable and Sustainable Energy Reviews, vol. 81. 2018. doi: 10.1016/j.rser.2017.08.020.
K. Zhao et al., “Efficient wastewater treatment and simultaneously electricity production using a photocatalytic fuel cell based on the radical chain reactions initiated by dual photoelectrodes,” J. Hazard. Mater., vol. 337, 2017, doi: 10.1016/j.jhazmat.2017.05.004.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2026 David Kevin

This work is licensed under a Creative Commons Attribution 4.0 International License.





