Literature Review: Effects of Palm Oil Fuel Ash Adsorbent Mass Variation on Adsorption Process Efficiency in Water Treatment
DOI:
https://doi.org/10.30595/rice.v5i1.414Keywords:
Palm Oil Fuel Ash, POFA, Adsorbent, Adsorption, Removal efficiencyAbstract
Palm Oil Fuel Ash (POFA) has excellent potential as an adsorbent for heavy metals, especially zinc (Zn), because it is able to provide a high absorption percentage. The purpose of this literature study is to systematically examine the effect of variations in the mass of Palm Oil Fuel Ash (POFA) adsorbent on the efficiency of the heavy metal adsorption process in water treatment, as well as to identify the most effective activator for POFA-based adsorbents based on the results of previous studies. The literature study method was carried out by reviewing and comparing relevant national and international scientific articles through Google Scholar, Garuda, and SINTA-accredited journal databases, with a focus on the relationship between POFA adsorbent mass and adsorption efficiency. Commonly used activators include NH₄Cl, HCl, NaOH, and KOH, with the best results varying for each type of POFA modification. Unmodified POFA showed optimum performance when activated using NH₄Cl, with an adsorption percentage reaching 98.65% at a mass of 10 grams, while zeolite POFA gave the highest results with HCl activator, namely 98.77% with a mass of only 2 grams. In contrast, silica POFA showed a lower adsorption capacity, with an adsorption percentage of 44.50% at a mass of 25 grams. Overall, these results indicate that POFA zeolite is the most effective adsorbent in the adsorption of zinc metal compared to unmodified POFA and silica POFA because it is able to achieve high efficiency with the use of less adsorbent mass.References
J. E. A. Liku, W. Mulya, M. K. Sipahutar, I. P. Sari, and N. Noeryanto, “Mengidentifikasi Sumber Pencemaran Air Limbah di Tempat Kerja,” EUNOIA J. Pengabdi. Masy., vol. 1, no. 1, pp. 14–19, 2022.
L. Dini, R. A. Kusumadewi, and R. Hadisoebroto, “Adsorpsi Logam Berat Krom (Cr) dan Zat Warna Menggunakan Adsorben Kulit Pisang Kepok dalam Air Limbah Batik,” J. Reka Lingkung., vol. 11, no. 1, pp. 37–48, 2023, doi: 10.26760/rekalingkungan.v11i1.37-48.
C. Ganapathy, K. Nivetha, E. Ohm Kumar, and T. Pratheep, “Wastewater Treatment Using Fly Ash,” Int. Res. J. Eng. Technol., vol. 5, no. 2, pp. 680–683, 2018.
S. Sulistia and A. C. Septisya, “Analisis Kualitas Air limbah Domestik Perkantoran,” JRL, vol. 12, no. 1, pp. 41–57, 2019.
M. Rofik and A. Mokhtar, “Pencemaran dalam Lingkungan Hidup,” Semin. Keinsinyuran, vol. 21, no. 2, pp. 102–105, 2021.
C. Novitasari, A. Sefentry, and M. Fatimura, “Pengaruh Fly Ash Batubara Sebagai Adsorben Pada Limbah Cair Kain Jumputan Palembang,” J. Teknol. dan Inov. Ind., vol. 4, no. 2, pp. 21–26, 2023, doi: 10.23960/jtii.v4i2.77.
F. Mubin, A. Binilang, and F. Halim, “Perencanaan Sistem Pengolahan Air Limbah Domestik di kelurahan Istiqlal Kota Manado,” J. Sipil Statik, vol. 4, no. 3, pp. 211–223, 2016.
H. Caniago, K. Rusba, N. Noeryanto, W. Mulya, and I. Pratamasari, “Efektivitas Pengawasan Pengelolaan Limbah Cair Industri di Dinas Lingkungan Hidup Kota Balikpapan,” J. Keselamatan, Kesehat. Kerja, dan Lindungan Lingkung., vol. 9, no. 2, pp. 788–796, 2023.
F. Abdilah, M. Hulupi, K. Keryanti, N. Nabilah, and T. H. Nabilah, “Sintesis Zn-BDC dengan Metode Sonokimia dan Aplikasinya Pada Proses Adsorpsi Ion Logam Pb2+,” React. J. Res. Chem. Eng., vol. 3, no. 1, pp. 10–16, 2022, doi: 10.52759/reactor.v3i1.48.
A. A. Putri, F. G. Permana, A. Wulandari, and R. Irawanto, “Respon Pertumbuhan Ipomoea Reptans Pada Media Tanam (Tanah dan Air) Terhadap Pencemar Timbal (Pb) dan Tembaga (Cu),” Pros. Semin. Nas. Sains dan Teknol., vol. 13, no. 1, pp. 14–24, 2023.
L. Y. Kurnianti, H. Haeruddin, and A. Rahman, “Analisis Beban dan Status Pencemaran BOD dan COD di Kali Asin Semarang,” J. Fish. Mar. Res., vol. 4, no. 3, pp. 379–388, 2020.
T. Widayatno, T. Yuliawati, and A. A. Susilo, “Adsorpsi Logam Berat (Pb) dari Limbah Cair dengan Adsorben Arang Bambu Aktif,” J. Teknol. Bahan Alam, vol. 1, no. 1, pp. 17–23, 2017.
I. S. M. Salleh, N. A. Mustazar, and H. W. Yussof, “Mercury Removal from Wastewater Using Palm Oil Fuel Ash,” MATEC Web Conf., vol. 150, no. 1, pp. 1–5, 2018, doi: 10.1051/matecconf/201815002007.
H. Zaini, C. A. Rahmahwati, and S. A. Bakar, “Study Wfektifitas Penyerapan Pb (II) di dalam Air Tercemar Pada Bioadsorben Kulit Kacang Tanah dan Ampas Tebu,” J. Vokasi, vol. 3, no. 1, pp. 12–17, 2019.
M. S. M. Yusof et al., “Arsenic Adsorption Mechanism On Palm Oil Fuel Ash (POFA) Powder Suspension,” J. Hazard. Mater., vol. 383, no. 1, pp. 1–10, 2020, doi: 10.1016/j.jhazmat.2019.121214.
A. F. Afifudin, A. Wulandari, and R. Irawanto, “Pencemaran Logam Berat di Air, Sedimen, dan Organisme pada Beberapa Sungai di Pulau Jawa, Indonesia: Tinjauan Literatur,” Environ. Pollut. J., vol. 4, no. 1, pp. 959–971, 2024.
R. R. Badu, W. R. Kunusa, N. I. R. Umadji, M. Z. Paramata, and A. A. M. S. A, “Pemanfaatan Fly Ash dan Bottom Ash Sebagai Adsorben dalam Menurunkan Parameter COD dan BOD pada Limbah Cair Tahu,” J. Serambi Eng., vol. 10, no. 2, pp. 13374–13380, 2025.
Kusmiyati, P. A. Listyanto, D. Vitasary, R. Indra, D. Islamica, and Hadiyanto, “Coal Bottom Ash and Activated Carbon for Removal of Vertigo Blue Dye in Batik Textile Waste Water: Adsorbent Characteristic, Isotherms, and Kinetics Studies,” Walailak J. Sci. Technol., vol. 14, no. 5, pp. 427–439, 2017.
I. E. Wijayanti and E. A. Kurniawati, “Studi Kinetika Adsorpsi Isoterm Persamaan Langmuir dan Freundlich Pada Abu Gosok Sebagai Adsorben,” EduChemia (Jurnal Kim. dan Pendidikan) Vol.4, vol. 4, no. 2, pp. 175–184, 2019, doi: 10.30870/educhemia.v4i2.6119.
W. R. Kunusa, R. R. Badu, N. I. R. Umadji, M. Z. Paramata, and R. I. Ibrahim, “Efektivitas Limbah PLTU : Penggunaan Fly Ash dan Bottom Ash Sebagai Adsorben untuk Menurunkan Kandungan TSS Limbah Cair Tahu,” J. Purifikasi, vol. 24, no. 1, pp. 52–58, 2025.
N. S. Fasihah, Y. Maryani, and H. Heriyanto, “Pengolahan Air Limbah Laundry Menggunakan Adsorbsi Cangkang Telur Ayam,” J. Ilm. Wahana Pendidik., vol. 8, no. 20, pp. 129–139, 2022.
P. S. Utama, R. Yamsaensung, and C. Sangwichien, “Silica Gel Derived From Palm Oil Mill Fly Ash,” Songklanakarin J. Sci. Technol., vol. 40, no. 1, pp. 121–126, 2018, doi: 10.14456/sjst-psu.2018.27.
E. P. O. Sitanggang, N. Kholiza, and W. D. Ivontianti, “Efektivitas Pengolahan Air Gambut Kota Pontianak dengan Adsorpsi Menggunakan Karbon Aktif dari Cangkang Buah Bintaro (Cerbera manghas),” Envirotek J. Ilm. Tek. Lingkung., vol. 14, no. 2, pp. 182–187, 2022.
M. H. Assegaf, R. Rosyani, and Z. Alamsyah, “Analisis Pemanfaatan Limbah Abu Kelapa Sawit Sebagai Adsorben dalam Menurunkan Logam Besi (Fe) pada Air Asam Tambang,” J. Ilm. Univ. Batanghari Jambi, vol. 24, no. 2, pp. 1327–1334, 2024, doi: 10.33087/jiubj.v24i2.4763.
I. Syafiqah, H. W. Yussof, A. A. M. Azoddein, S. Chandraseagar, and F. W. Ishak, “A Factorial Analysis Study on Removal of Mercury by Palm Oil Fuel Ash Adsorbent,” Chem. Eng. Trans., vol. 56, no. 11, pp. 1501–1506, 2017, doi: 10.3303/CET1756251.
L. Darmayanti and A. Adawiyah, “Innovative Use of Palm Oil Fly Ash-Based Zeolite for Zinc ( II ) Removal from Wastewater,” J. Ilmu Lingkung., vol. 23, no. 5, pp. 1353–1358, 2025, doi: 10.14710/jil.23.5.1353-1358.
L. Darmayanti and L. Indriani, “Adsorption of Cadmium (Cd) Metal in Solution Using Pofa-Based Zeolite (Palm Oil Fly Ash),” EduChemia J. Kim. dan Pendidik., vol. 9, no. 2, pp. 176–187, 2024, doi: 10.30870/educhemia.v9i2.24846.
S. D. Arini, L. Darmayanti, and D. Fitria, “Faktor-Faktor yang Mempengaruhi Proses Ekstraksi Silika Sebagai Adsorben untuk Penyisihan Zat Organik Pada Air Gambut,” JOM FTEKNIK, vol. 7, no. 2, pp. 1–6, 2020.
F. R. Yuni, L. Darmayanti, and D. Fitria, “Pengaruh Rasio Padat/Cair dan Waktu Pengadukan pada Proses Ekstraksi Silika dari Palm Oil Fly Ash (POFA),” Al-Ard J. Tek. Lingkung., vol. 6, no. 2, pp. 60–67, 2021, doi: 10.29080/alard.v6i2.1065.
N. Setyawan, Hoerudin, and A. Wulanawati, “Simple Extraction of Silica Nanoparticles From Rice Husk Using Technical Grade Solvent: Effect of Volume and Concentration,” IOP Conf. Ser. Earth Environ. Sci., vol. 309, no. 1, pp. 1–8, 2019, doi: 10.1088/1755-1315/309/1/012032.
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